Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(I) complexes linked to (metallo)porphyrins - Institut de Chimie Moléculaire de l'Université de Bourgogne Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2022

Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(I) complexes linked to (metallo)porphyrins

Résumé

Electronic and steric properties of NHC ligands functionalized with porphyrins were investigated. When porphyrins are used as NHCwingtips, nickel(II) in the macrocyle significantly improves the catalytic activity of the neighbouring NHC-Rh(I) complex in the conjugate addition of phenylboronic acid to cyclohexen-2-one.
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Origine : Publication financée par une institution

Dates et versions

hal-03841395 , version 1 (07-11-2022)

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Ludivine Poyac, Stefano Scoditti, Xavier Dumail, Michel Granier, Sébastien Clément, et al.. Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(I) complexes linked to (metallo)porphyrins. Chemical Communications, In press, ⟨10.1039/D2CC05547C⟩. ⟨hal-03841395⟩
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