Preparation of cobalt polyporphine and its catalytic properties in oxygen electroreduction

D. V. Konev 1, 2, * K. V. Lizgina 3, * D. K. Khairullina 1 M. A. Shamraeva 3 C. H. Devillers 4 M. A. Vorotyntsev 1, 2, 4, 3
* Auteur correspondant
1 Mendeleev University of Chemical Technology of Russia
2 Institute for Problems of Chemical Physics
3 MSU - Lomonosov Moscow State University
4 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]
Abstract : A new member of the polyporphine series-cobalt polyporphine of type I (pCoP-I)-was prepared from the starting magnesium polyporphine of type I (pMgP-I) by ion exchange, i.e. by sequential processing of the pMgP-I polymer film on the electrode surface with solutions of trifluoroacetic acid (forming metalfree polyporphine of type I, pH(2)P-I) and cobalt(II) acetate in organic solvents. The completeness of each stage of ion exchange can be judged from the change in the electrochemical and spectral characteristics of the obtained polymer films of unsubstituted porphine (?H2P-I) and cobalt porphine (pCoP-I) of type I. Oxidative transformation of this polyporphine pCoP-I was performed, which led to the formation of additional bonds between the neighboring porphine units in the polymer film (transition of polymer of type I into polymer of type II, pCoP-II). The behavior of the polymer films of cobalt polyporphine of types I and II in oxygen electroreduction was studied. The films showed catalytic activity in this process.
Keywords : electropolymerization porphine metal porphines conductive polymer oxygen electroreduction polymer-modified electrodes electrochemical properties films metalloporphyrins porphyrins reduction electropolymerization pyropolymer oxidation polymers bandgap
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https://hal-univ-bourgogne.archives-ouvertes.fr/hal-01404220
Contributeur : Icmub - Université de Bourgogne <>
Soumis le : lundi 28 novembre 2016 - 15:03:27
Dernière modification le : mercredi 4 septembre 2019 - 17:36:02

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UNIV-BOURGOGNE | CNRS | INC-CNRS | ICMUB

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D. V. Konev, K. V. Lizgina, D. K. Khairullina, M. A. Shamraeva, C. H. Devillers, et al.. Preparation of cobalt polyporphine and its catalytic properties in oxygen electroreduction. Elektrokhimiya / Russian Journal of Electrochemistry, MAIK Nauka/Interperiodica, 2016, 52 (8), pp.778 - 787. ⟨10.1134/S1023193516060069⟩. ⟨hal-01404220⟩

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