Electropolymerization of magnesium 5,15-di(n-methoxyphenyl)porphine

D. V. Konev; K. V. Lizgina; O. I. Istakova; V. E. Baulin; I. P. Kalashnikova; C. H. Devillers; M. A. Vorotyntsev

doi:10.1134/S1023193516120077

Article dans une revue

Electropolymerization of magnesium 5,15-di(n-methoxyphenyl)porphine

D. V. Konev ^{1, 2, *} K. V. Lizgina ³ O. I. Istakova ^{2, 1} V. E. Baulin ^{4, 5} I. P. Kalashnikova ^{4, 5} C. H. Devillers ⁶ M. A. Vorotyntsev ^{2, 3, 6, 1}

* Auteur correspondant

1 Institute of Problems of Chemical Physics

2 Mendeleev University of Chemical Technology of Russia

3 Department of Chemistry, Lomonosov Moscow State University

4 Institute of Physiologically Active Compounds

5 Frumkin Institute of Physical Chemistry and Electrochemistry

6 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]

Abstract : The process of electroxidative polymerization of magnesium 5,15-di(N-methoxyphenyl)porphine MgP(MeOPh)(2) is studied. The presence of substituents in positions 5 and 15 of the porphine macroring makes reactive two of its four meso positions, which allows new bonds to be formed only in the opposite positions 10 and 20. As a result, the process of electropolymerization of this substituted monomer at its oxidation can produce only linear chains, in contrast to unsubstituted magnesium porphine MgP for which the polymer structure can both be linear and contain zigzag and/or cruciform fragments.

Keywords : porphine fabrication oxidation electroactive materials electropolymerization unsubstituted porphine 5 15-substituted porphine conjugated polymer porphyrin polyporphine polymers mg(ii) ion

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Article dans une revue

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Chimie

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https://hal-univ-bourgogne.archives-ouvertes.fr/hal-01428046
Contributeur : Icmub - Université de Bourgogne <>
Soumis le : vendredi 6 janvier 2017 - 12:05:13
Dernière modification le : mardi 24 novembre 2020 - 12:56:02

Electropolymerization of magnesium 5,15-di(n-methoxyphenyl)porphine

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