Crystal structure of the diglycidyl ether of eugenol

Abstract : The diepoxy monomer, C13H16O4 {DGE-Eu; systematic name: 2-[3-methoxy-4-(oxiran-2-ylmethoxy)benzyl]oxirane}, was synthesized from eugenol by a three-step reaction. It consists of a 1,2,4-trisubstituted benzene ring substituted by diglycidyl ether, a methoxy group and a methyloxirane group. The three-membered oxirane rings are inclined to the benzene ring by 61.0 (3) and 27.9 (3)degrees. The methylene C atom of one of the two terminal epoxide rings is positionally disordered [refined occupancy ratio = 0.69 (1):0.31 (1)]. In the crystal, molecules are linked by C-H center dot center dot center dot O hydrogen bonds, forming layers parallel to the ab plane. The layers are linked by C-H center dot center dot center dot pi interactions, forming a three-dimensional network.
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Acta crystallographica. Section E, Crystallographic communications, International Union of Crystallography, 2017, 73 (5), pp.694 - 697. 〈https://www.ncbi.nlm.nih.gov/pubmed/28529778〉. 〈10.1107/S2056989017005370〉
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https://hal-univ-bourgogne.archives-ouvertes.fr/hal-01543417
Contributeur : Ub_drive Université de Bourgogne <>
Soumis le : mardi 20 juin 2017 - 18:54:02
Dernière modification le : vendredi 6 juillet 2018 - 15:06:09

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Jordan Vigier, Camille François, Sylvie Pourchet, Gilles Boni, Laurent Plasseraud, et al.. Crystal structure of the diglycidyl ether of eugenol. Acta crystallographica. Section E, Crystallographic communications, International Union of Crystallography, 2017, 73 (5), pp.694 - 697. 〈https://www.ncbi.nlm.nih.gov/pubmed/28529778〉. 〈10.1107/S2056989017005370〉. 〈hal-01543417〉

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