A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification

Abstract : A general synthesis of highly functionalized ferrocenes, which include (P,B)- and (N,B)-ambiphiles, has been developed at a multigram scale. Diastereoselective stepwise modification of di-tert-butylated ferrocenes included the unprecedented separation of electroactive species. Bulky alkyl groups on ferrocenes ensure planar chirality of ambiphiles and enforce closer proximity of antagonist Lewis functions.
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https://hal-univ-bourgogne.archives-ouvertes.fr/hal-01559338
Contributeur : Icmub - Université de Bourgogne <>
Soumis le : lundi 10 juillet 2017 - 16:03:31
Dernière modification le : jeudi 4 avril 2019 - 10:18:05

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Emmanuel Lerayer, Patrice Renaut, Julien Roger, Nadine Pirio, Hélène Cattey, et al.. A general diastereoselective synthesis of highly functionalized ferrocenyl ambiphiles enabled on a large scale by electrochemical purification. Chemical Communications, Royal Society of Chemistry, 2017, 53 (44), pp.6017 - 6020. ⟨http://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc02469j/unauth#!divAbstract⟩. ⟨10.1039/c7cc02469j⟩. ⟨hal-01559338⟩

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