Abstract : A general synthesis of highly functionalized ferrocenes, which include (P,B)- and (N,B)-ambiphiles, has been developed at a multigram scale. Diastereoselective stepwise modification of di-tert-butylated ferrocenes included the unprecedented separation of electroactive species. Bulky alkyl groups on ferrocenes ensure planar chirality of ambiphiles and enforce closer proximity of antagonist Lewis functions.
https://hal-univ-bourgogne.archives-ouvertes.fr/hal-01559338
Contributeur : Icmub - Université de Bourgogne
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Soumis le : lundi 10 juillet 2017 - 16:03:31
Dernière modification le : jeudi 11 janvier 2018 - 06:21:16
