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Article dans une revue
A Very Low Band Gap Diketopyrrolopyrrole-Porphyrin Conjugated Polymer
Abstract : A porphyrin-diketopyrrolopyrrole-containing polymer (poly(porphyrin-diketopyrrolopyrrole) (PPDPP)) shows impressive molar absorption coefficients from lambda=300 to 1000 nm. The photophysical and structural properties of PPDPP have been studied. With PPDPP as the electron donor and [ 6,6]phenyl C-71 butyric acid methyl ester (PC71BM) as the electron acceptor, the bulk heterojunction polymer solar cell showed overall power conversion efficiencies of 4.18 and 6.44% for as-cast and two-step annealing processed PPDPP: PC71BM (1: 2) active layers, respectively. These results are quite impressive for porphyrin-containing polymers, especially when directly included in the pi-conjugated backbone, and offer interesting perspectives for the design of new materials based on this chromophore.
https://hal-univ-bourgogne.archives-ouvertes.fr/hal-01562019
Contributeur : Icmub - Université de Bourgogne <>
Soumis le : jeudi 13 juillet 2017 - 14:50:02
Dernière modification le : mercredi 10 février 2021 - 11:56:04
Contributeur : Icmub - Université de Bourgogne <>
Soumis le : jeudi 13 juillet 2017 - 14:50:02
Dernière modification le : mercredi 10 février 2021 - 11:56:04