Synthesis of Bioinspired Curcuminoid Small Molecules for Solution-Processed Organic Solar Cells with High Open-Circuit Voltage

Florence Archet; Dandan Yao; Sylvain Chambon; Mamatimin Abbas; Anthony D’aléo; Gabriel Canard; Miguel Ponce-Vargas; Elena Zaborova; Boris Le Guennic; Guillaume Wantz; Frédéric Fages

doi:10.1021/acsenergylett.7b00157

Synthesis of Bioinspired Curcuminoid Small Molecules for Solution-Processed Organic Solar Cells with High Open-Circuit Voltage

Florence Archet ¹ Dandan Yao ² Sylvain Chambon ¹ Mamatimin Abbas ¹ Anthony D’aléo ² Gabriel Canard ² Miguel Ponce-Vargas ³ Elena Zaborova ² Boris Le Guennic ³ Guillaume Wantz ^{1, *} Frédéric Fages ^{2, *}

* Auteur correspondant

1 IMS - Laboratoire de l'intégration, du matériau au système

2 CINaM - Centre Interdisciplinaire de Nanoscience de Marseille

3 ISCR - Institut des Sciences Chimiques de Rennes

Abstract : Borondifluoride complexes of curcuminoid derivatives end-capped with triphenylamine groups were designed for solution-processed bulk-heterojunction organic solar cells. They were obtained very simply in a one-pot synthesis from cheap building blocks. Compared to push-pull systems based on borondifluoride complexes of hydroxychalcones, curcuminoids present the donor-accept-or-donor electronic structure and exhibit significantly improved chemical and thermal stability and photovoltaic performance. Indeed, power conversion efficiency up to 4.14% and high open-circuit voltage over 1.0 V have been achieved using PC61BM as acceptor.

Keywords : charge separation efficiency photovoltaics complexes

Type de document :

Article dans une revue

ACS Energy Letters, 2017, 2 (6), pp.1303-1307. 〈10.1021/acsenergylett.7b00157〉

Domaine :

Chimie / Chimie organique

Liste complète des métadonnées

https://hal-univ-bourgogne.archives-ouvertes.fr/hal-01563209
Contributeur : Icmub - Université de Bourgogne <>
Soumis le : jeudi 7 septembre 2017 - 15:58:27
Dernière modification le : mercredi 20 juin 2018 - 01:24:23

Synthesis of Bioinspired Curcuminoid Small Molecules for Solution-Processed Organic Solar Cells with High Open-Circuit Voltage

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Synthesis of Bioinspired Curcuminoid Small Molecules for Solution-Processed Organic Solar Cells with High Open-Circuit Voltage

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Citation

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351

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