New n-type molecular semiconductor–doped insulator (MSDI) heterojunctions combining a triphenodioxazine (TPDO) and the lutetium bisphthalocyanine (LuPc2) for ammonia sensing

Amélie Wannebroucq (1) , Guillaume Gruntz (2) , Jean-Moïse Suisse (1) , Yohann Nicolas (2) , Rita Meunier-Prest (1) , Mickaël Mateos (1) , Thierry Toupance (3) , Marcel Bouvet (1)

1 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]
2 ISM - Institut des Sciences Moléculaires
3 LCOO - Laboratoire de chimie organique et organométallique

Molecular semiconductor–doped insulator (MSDI) heterojunctions were designed using a new family of sublayers, namely triphenodioxazines (TPDO). The device obtained by combining the tetracyano triphenodioxazine bearing two triisopropylsilylethynyl moieties as a sublayer with the lutetium bisphthalocyanine (LuPc2) as a top layer showed a nonlinear current–voltage characteristic independent of the sign of the polarization, which is the signature of MSDI heterojunctions. Thus, a TPDO was used in a chemical sensor for the first time. Despite LuPc2 being the only material exposed to the atmosphere, the positive response of the device under ammonia revealed the key role played by the n-type TPDO sublayer. The device exhibits a response stable over time and can operate in a broad range of relative humidity.

Mots clés: Triphenodioxazine; Molecular materials; Heterojunctions; Conductometric transducer; Ammonia

Domaines: Chimie analytique; Electronique

Amélie Wannebroucq, Guillaume Gruntz, Jean-Moïse Suisse, Yohann Nicolas, Rita Meunier-Prest, et al.. New n-type molecular semiconductor–doped insulator (MSDI) heterojunctions combining a triphenodioxazine (TPDO) and the lutetium bisphthalocyanine (LuPc2) for ammonia sensing. Sensors and Actuators B: Chemical, 2018, 255 (Part 2), pp.1694-1700. ⟨10.1016/j.snb.2017.08.184⟩. ⟨hal-02295973⟩