Input of P, N-(phosphanyl, amino)-ferrocene hybrid derivatives in late transition metals catalysis

Nejib Dwadnia (1) , Julien Roger (1) , Nadine Pirio (1) , Hélène Cattey (1) , Jean-Cyrille Hierso (1, 2)

1 ICMUB - Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon]
2 IUF - Institut universitaire de France

Unequally functionalized ferrocenes give access to valuable hemilabile reactivity in catalytic reaction. We address the synthesis of hybrid (P, N)-ferrocenyl compounds for which recent catalytic breakthrough applications have been reported, transversely in late transition metals chemistry. Palladium, nickel, rhodium, iridium, and emerging iron and gold catalysis are illustrated from selected examples, which include CC bond formation from cross-coupling and polymerization, allylic substitution, cyanation, hydroformylation, CH arylation and silylation and hydrogenation reactions.

Mots clés: Ferrocene; Polyfunctionalized ligands; Hemilabile hybrids; Aminophosphines; Homogeneous catalysis; Late transition metals; oxazoline-containing ligands; asymmetric catalysis; ethylene oligomerization; p; n ligands; structural-characterization; ferrocenyl ligands; nickel-complexes; beta-ketoesters; chiral ligands; simple ketones

Domaines: Chimie; Chimie inorganique

Nejib Dwadnia, Julien Roger, Nadine Pirio, Hélène Cattey, Jean-Cyrille Hierso. Input of P, N-(phosphanyl, amino)-ferrocene hybrid derivatives in late transition metals catalysis. Coordination Chemistry Reviews, 2018, 355, pp.74 - 100. ⟨10.1016/j.ccr.2017.07.015⟩. ⟨hal-01823662⟩